<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Guillemot G</dc:creator>
  <dc:creator>Castellano B</dc:creator>
  <dc:creator>Prangé T</dc:creator>
  <dc:creator>Solari E</dc:creator>
  <dc:creator>Floriani C</dc:creator>
  <dc:date>2007</dc:date>
  <dc:description xmlns:ns0="xml" ns0:lang="en">The synthesis and structural characterization of a samarium-dinitrogen complex supported by a calix[4]arene ligand in which the N-N bond distance has been stretched to 1.611(16) Angstrom are described. The central mu(3)-eta(2):eta(2):eta(2)-hydrazido tetraanion formed is bonded to three Sm(III) centers with an overall butterfly-type arrangement.</dc:description>
  <dc:identifier>https://sonar.ch/global/documents/102319</dc:identifier>
  <dc:language>eng</dc:language>
  <dc:relation>info:eu-repo/semantics/altIdentifier/doi/10.1021/ic700787d</dc:relation>
  <dc:relation>info:eu-repo/semantics/altIdentifier/pmid/17542578</dc:relation>
  <dc:source>Inorganic chemistry. - 2007</dc:source>
  <dc:subject xmlns:ns1="xml" ns1:lang="en">Calixarenes</dc:subject>
  <dc:subject xmlns:ns2="xml" ns2:lang="en">Lanthanoid Series Elements</dc:subject>
  <dc:subject xmlns:ns3="xml" ns3:lang="en">Molecular Structure</dc:subject>
  <dc:subject xmlns:ns4="xml" ns4:lang="en">Nitrogen</dc:subject>
  <dc:subject xmlns:ns5="xml" ns5:lang="en">Oxidation-Reduction</dc:subject>
  <dc:subject xmlns:ns6="xml" ns6:lang="en">Phenols</dc:subject>
  <dc:subject xmlns:ns7="xml" ns7:lang="en">Samarium</dc:subject>
  <dc:title xmlns:ns8="xml" ns8:lang="en">Use of calix[4]arenes in the redox chemistry of lanthanides: the reduction of dinitrogen by a calix[4]arene-samarium complex.</dc:title>
  <dc:type>http://purl.org/coar/resource_type/c_6501</dc:type>
</oai_dc:dc>