<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Camp C</dc:creator>
  <dc:creator>Chatelain L</dc:creator>
  <dc:creator>Mougel V</dc:creator>
  <dc:creator>Pécaut J</dc:creator>
  <dc:creator>Mazzanti M</dc:creator>
  <dc:date>2015</dc:date>
  <dc:description xmlns:ns0="xml" ns0:lang="en">Uranyl(VI), uranyl(V), and uranium(IV) complexes supported by ferrocene-based tetradentate Schiff-base ligands were synthesized, and their solid-state and solution structures were determined. The redox properties of all complexes were investigated by cyclic voltammetry. The bulky salfen-(t)Bu2 allows the preparation of a stable uranyl(V) complex, while a stable U(IV) bis-ligand complex is obtained from the salt metathesis reaction between [UI4(OEt2)2] and K2salfen. The reduction of the [U(salfen)2] complex leads to an unprecedented intramolecular reductive coupling of the Schiff-base ligand resulting in a C-C bond between the two ferrocene-bound imino groups.</dc:description>
  <dc:identifier>https://sonar.ch/global/documents/166457</dc:identifier>
  <dc:language>eng</dc:language>
  <dc:relation>info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.inorgchem.5b00467</dc:relation>
  <dc:relation>info:eu-repo/semantics/altIdentifier/pmid/26010406</dc:relation>
  <dc:source>Inorganic chemistry. - 2015</dc:source>
  <dc:title xmlns:ns1="xml" ns1:lang="en">Ferrocene-Based Tetradentate Schiff Bases as Supporting Ligands in Uranium Chemistry.</dc:title>
  <dc:type>http://purl.org/coar/resource_type/c_6501</dc:type>
</oai_dc:dc>