<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Barluzzi L</dc:creator>
  <dc:creator>Scopelliti R</dc:creator>
  <dc:creator>Mazzanti M</dc:creator>
  <dc:date>2020</dc:date>
  <dc:description xmlns:ns0="xml" ns0:lang="en">Terminal uranium nitrides have so far proven impossible to isolate by photolysis of azides. Here we report the second ever example of an isolated terminal uranium(VI) nitride. We show that the terminal nitride [NBu4][U(OSi(OtBu)3)4(N)], 3, can be prepared upon photolysis with UV light of the U(IV) azide analogue. This is achieved by careful tailoring of the azide precursor and of the reaction conditions. Complex 3 is stable under ambient conditions but reacts readily with electrophiles (H+ and CO).</dc:description>
  <dc:identifier>https://sonar.ch/global/documents/282296</dc:identifier>
  <dc:language>eng</dc:language>
  <dc:relation>info:eu-repo/semantics/altIdentifier/doi/10.1021/jacs.0c09814</dc:relation>
  <dc:relation>info:eu-repo/semantics/altIdentifier/pmid/33119306</dc:relation>
  <dc:source>Journal of the American Chemical Society. - 2020</dc:source>
  <dc:subject xmlns:ns1="xml" ns1:lang="en">Colloid and Surface Chemistry</dc:subject>
  <dc:subject xmlns:ns2="xml" ns2:lang="en">Biochemistry</dc:subject>
  <dc:subject xmlns:ns3="xml" ns3:lang="en">General Chemistry</dc:subject>
  <dc:subject xmlns:ns4="xml" ns4:lang="en">Catalysis</dc:subject>
  <dc:title xmlns:ns5="xml" ns5:lang="en">Photochemical Synthesis of a Stable Terminal Uranium(VI) Nitride.</dc:title>
  <dc:type>http://purl.org/coar/resource_type/c_6501</dc:type>
</oai_dc:dc>