Dichlorido[1-(2-chloro-eth-yl)-3-(pyridin-4-ylmethyl-κN)urea](η-hexa-methyl-benzene)-ruthenium(II) chloro-form monosolvate.
- Auzias M Institut de Chimie, Université de Neuchâtel, Avenue de Bellevaux 51, CH-2000 Neuchâtel, Switzerland.
- Süss-Fink G
- Therrien B
- 2012-01-06
Published in:
- Acta crystallographica. Section E, Structure reports online. - 2011
English
The Ru(II) atom in the title compound, [RuCl(2)(C(12)H(18))(C(9)H(12)ClN(3)O)]·CHCl(3), exhibits a typical piano-stool coordination, defined by a hexa-methyl-benzene ligand, two chloride ligands and a pyridyl-urea ligand coordinated through the pyridine N atom. In the crystal, a dimeric structure is observed due to two strong N-H⋯Cl inter-actions between the NH groups of urea and the two chloride ligands of neighbouring mol-ecules. In addition, the C=O group of the urea moiety inter-acts with the solvent mol-ecule through weak C-H⋯O interactions.
- Language
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- English
- Open access status
- gold
- Identifiers
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- DOI 10.1107/S1600536811043728
- PMID 22219839
- Persistent URL
- https://sonar.ch/global/documents/784
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