Journal article
Preparation and properties of lithium and sodium peroxynitrite.
- Sturzbecher-Höhne M Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zurich, 8093 Zürich, Switzerland.
- Kissner R
- Nauser T
- Koppenol WH
- 2009-06-24
Published in:
- Chemical research in toxicology. - 2008
Chromatography, Ion Exchange
Ion Exchange
Lithium Compounds
Oxidants
Peroxynitrous Acid
Quaternary Ammonium Compounds
Spectrometry, Mass, Electrospray Ionization
English
We describe the preparation of aqueous solutions of LiONOO and NaONOO from (Me4N)ONOO. An aqueous solution of analytically pure, commercially available (Me4N)ONOO is applied to an Amberlyst 15 column at 4 degrees C, and the Me4N+ is rapidly (in 20 min) exchanged against Li+ or Na+. The exchanged peroxynitrite is produced in yields of ca. 90% with a nitrite content of 5-6%.
- Language
-
- English
- Open access status
- closed
- Identifiers
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- DOI 10.1021/tx800279n
- PMID 19548349
- Persistent URL
- https://sonar.ch/global/documents/123705
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