Hydrogen evolution at liquid-liquid interfaces.
- Hatay I Laboratoire d'Electrochimie Physique et Analytique, Ecole Polytechnique Fédérale de Lausanne, Station 6, 1015 Lausanne, Switzerland.
- Su B
- Li F
- Partovi-Nia R
- Vrubel H
- Hu X
- Ersoz M
- Girault HH
- 2009-06-05
Published in:
- Angewandte Chemie (International ed. in English). - 2009
English
Blowing bubbles: Hydrogen evolution by proton reduction with [(C(5)Me(5))(2)Fe] occurs at a soft interface between water and 1,2-dichloroethane (DCE). The reaction proceeds by proton transfer assisted by [(C(5)Me(5))(2)Fe] across the water-DCE interface with subsequent proton reduction in DCE. The interface essentially acts as a proton pump, allowing hydrogen evolution by directly using the aqueous proton.
- Language
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- English
- Open access status
- green
- Identifiers
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- DOI 10.1002/anie.200901757
- PMID 19496092
- Persistent URL
- https://sonar.ch/global/documents/155737
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