Journal article
Ferrocene-Based Tetradentate Schiff Bases as Supporting Ligands in Uranium Chemistry.
- Camp C †Univ. Grenoble Alpes, INAC-LCIB, RICC, and §CEA, INAC-LCIB F-38000 Grenoble, France.
- Chatelain L †Univ. Grenoble Alpes, INAC-LCIB, RICC, and §CEA, INAC-LCIB F-38000 Grenoble, France.
- Mougel V †Univ. Grenoble Alpes, INAC-LCIB, RICC, and §CEA, INAC-LCIB F-38000 Grenoble, France.
- Pécaut J †Univ. Grenoble Alpes, INAC-LCIB, RICC, and §CEA, INAC-LCIB F-38000 Grenoble, France.
- Mazzanti M ‡Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland.
- 2015-05-27
Published in:
- Inorganic chemistry. - 2015
English
Uranyl(VI), uranyl(V), and uranium(IV) complexes supported by ferrocene-based tetradentate Schiff-base ligands were synthesized, and their solid-state and solution structures were determined. The redox properties of all complexes were investigated by cyclic voltammetry. The bulky salfen-(t)Bu2 allows the preparation of a stable uranyl(V) complex, while a stable U(IV) bis-ligand complex is obtained from the salt metathesis reaction between [UI4(OEt2)2] and K2salfen. The reduction of the [U(salfen)2] complex leads to an unprecedented intramolecular reductive coupling of the Schiff-base ligand resulting in a C-C bond between the two ferrocene-bound imino groups.
- Language
-
- English
- Open access status
- closed
- Identifiers
-
- DOI 10.1021/acs.inorgchem.5b00467
- PMID 26010406
- Persistent URL
- https://sonar.ch/global/documents/166457
Statistics
Document views: 28
File downloads: