Back
One-Step Synthesis of Aliphatic Potassium Acyltrifluoroborates (KATs) from Organocuprates.
Journal article

One-Step Synthesis of Aliphatic Potassium Acyltrifluoroborates (KATs) from Organocuprates.

  • Liu SM Laboratorium für Organische Chemie, Department of Chemistry and Applied Biosciences , ETH Zürich , 8093 Zürich , Switzerland.
  • Wu D Laboratorium für Organische Chemie, Department of Chemistry and Applied Biosciences , ETH Zürich , 8093 Zürich , Switzerland.
  • Bode JW Laboratorium für Organische Chemie, Department of Chemistry and Applied Biosciences , ETH Zürich , 8093 Zürich , Switzerland.
  • 2018-04-06
Published in:
  • Organic letters. - 2018
Physical and Theoretical Chemistry
Organic Chemistry
Biochemistry
English A one-step synthesis of aliphatic KATs from organocuprates is reported. Organolithium and organomagnesium reagents were readily transmetalated onto Cu(I) and coupled with a KAT-forming reagent to yield the respective aliphatic KAT. The protocol is suitable for primary, secondary and-for the first time-tertiary alkyl substrates. These protocols considerably expand the range of KATs that can be readily accessed in one step from commercially available starting materials.
Language
  • English
Open access status
closed
Identifiers
Persistent URL
https://sonar.ch/global/documents/187985
Statistics
Document views: 15 File downloads: