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Ni(II)-catalyzed enantioselective Nazarov cyclizations.
Journal article

Ni(II)-catalyzed enantioselective Nazarov cyclizations.

  • Walz I Department of Chemistry and Applied Biosciences, Swiss Federal Institute of Technology, ETH Zurich, CH-8093 Zurich, Switzerland.
  • Togni A
  • 2008-09-20
Published in:
  • Chemical communications (Cambridge, England). - 2008
Catalysis
Crystallography, X-Ray
Cyclization
Ketones
Ligands
Models, Molecular
Molecular Structure
Nickel
Stereoisomerism
English Nazarov cyclizations are catalyzed by a dicationic Ni(II) complex containing the chiral tridentate phosphine Pigiphos; the catalyst exerts a high degree of torquoselectivity and affords the products in up to 88% ee.
Language
  • English
Open access status
closed
Identifiers
Persistent URL
https://sonar.ch/global/documents/191156
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