Tetra-ethyl-ammonium tricarbonyl-chlorido(isoquinoline-1-carboxyl-ato-κN,O)technetate(I).
- Schmalle HW Anorganisch-Chemisches Institut der Universität Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland.
- Alberto R
- 2011-01-05
Published in:
- Acta crystallographica. Section E, Structure reports online. - 2008
English
The asymmetric unit of the title compound, (C(8)H(20)N)[Tc(C(10)H(6)NO(2))Cl(CO)(3)], consists of two crystallographically independent technetium complexes related via a pseudo-inversion centre and two tetra-ethyl-ammonium cations. The Tc atoms have slightly distorted octa-hedral coordination geometries, and they are linked with the cations by inter-molecular C-H⋯O and C-H⋯Cl hydrogen-bonding contacts, forming two-dimensional columns, which lie approximately parallel to (001) in the crystal structure. The isochinolate (isoquinoline-1-carboxyl-ate) ligands link the columns by partial π-π stacking [centroid-centroid distance 4.3733 (11) Å], forming a three-dimensional network structure.
- Language
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- English
- Open access status
- gold
- Identifiers
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- DOI 10.1107/S160053680802713X
- PMID 21201647
- Persistent URL
- https://sonar.ch/global/documents/191665
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