Journal article
Ruthenium Nitrides: Redox Chemistry and Photolability of the Ru-Nitrido Group.
- Bonomo L Institut de Chimie Minérale et Analytique Université de Lausanne BCH, 1015 Lausanne (Switzerland) Fax: (+41) 21-692-3905.
- Solari E Institut de Chimie Minérale et Analytique Université de Lausanne BCH, 1015 Lausanne (Switzerland) Fax: (+41) 21-692-3905.
- Scopelliti R Institut de Chimie Minérale et Analytique Université de Lausanne BCH, 1015 Lausanne (Switzerland) Fax: (+41) 21-692-3905.
- Floriani C Institut de Chimie Minérale et Analytique Université de Lausanne BCH, 1015 Lausanne (Switzerland) Fax: (+41) 21-692-3905.
- 2018-05-02
Published in:
- Angewandte Chemie (International ed. in English). - 2001
English
Tunable electrophilicity/nucleophilicity by means of the redox properties of the Ru≡N group and reversible interconversion of mononuclear and dinuclear species as a result of the photolability of the Ru=N=Ru group are characteristic of the nitrido derivatives of Ru porphyrinogens. For example, 2, the product of reversible reduction of a Ru≡N precusor, reacts with 1 in the dark to form 3, which undergoes photocleavage to 1 and 2.
- Language
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- English
- Open access status
- closed
- Identifiers
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- DOI 10.1002/1521-3773(20010702)40:13<2529::AID-ANIE2529>3.0.CO;2-B
- PMID 29712295
- Persistent URL
- https://sonar.ch/global/documents/20456
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