Journal article
Electric-Field-Mediated Reversible Transformation between Supramolecular Networks and Covalent Organic Frameworks.
- Cai ZF Department of Chemistry, Division of Molecular Imaging and Photonics , KU Leuven , Celestijnenlaan 200F , B-3001 Leuven , Belgium.
- Zhan G Department of Chemistry, Division of Molecular Imaging and Photonics , KU Leuven , Celestijnenlaan 200F , B-3001 Leuven , Belgium.
- Daukiya L Department of Chemistry, Division of Molecular Imaging and Photonics , KU Leuven , Celestijnenlaan 200F , B-3001 Leuven , Belgium.
- Eyley S Department of Chemical Engineering, Renewable Materials and Nanotechnology Group, Campus Kortrijk , KU Leuven , Etienne Sabbelaan 53 , 8500 Kortrijk , Belgium.
- Thielemans W Department of Chemical Engineering, Renewable Materials and Nanotechnology Group, Campus Kortrijk , KU Leuven , Etienne Sabbelaan 53 , 8500 Kortrijk , Belgium.
- Severin K Institut des Sciences et Ingénierie Chimiques , Ecole Polytechnique Fédérale de Lausanne (EPFL) , 1015 Lausanne , Switzerland.
- De Feyter S Department of Chemistry, Division of Molecular Imaging and Photonics , KU Leuven , Celestijnenlaan 200F , B-3001 Leuven , Belgium.
- 2019-07-09
Published in:
- Journal of the American Chemical Society. - 2019
English
By using an oriented electric field in a scanning tunneling microscope, one can locally control the condensation of boronic acids at the liquid/solid interface. The phase transition between self-assembled molecular networks and covalent organic frameworks is controlled by changing the polarity of the applied bias. The electric-field-induced phase transformation is reversible under ambient conditions.
- Language
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- English
- Open access status
- closed
- Identifiers
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- DOI 10.1021/jacs.9b05265
- PMID 31280563
- Persistent URL
- https://sonar.ch/global/documents/20473
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