Journal article
Pummerer fragmentation vs. pummerer rearrangement: a mechanistic analysis.
- Laleu B Department of Organic Chemistry, University of Geneva, Quai E. Ansermet 30, CH-1211 Geneva 4, Switzerland.
- Machado MS
- Lacour J
- 2006-10-03
Published in:
- Chemical communications (Cambridge, England). - 2006
English
Depending upon the nature of the substituent at the beta-position of the sulfoxide moiety, a Pummerer reaction can be oriented "at will" towards Calpha-H (rearrangement) or Calpha-Cbeta (fragmentation) bond cleavage.
- Language
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- English
- Open access status
- closed
- Identifiers
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- DOI 10.1039/b605187a
- PMID 17009463
- Persistent URL
- https://sonar.ch/global/documents/21089
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