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Construction of Quaternary Stereocenters by Palladium-Catalyzed Carbopalladation-Initiated Cascade Reactions.
Journal article

Construction of Quaternary Stereocenters by Palladium-Catalyzed Carbopalladation-Initiated Cascade Reactions.

  • Ping Y The Institute for Advanced Studies, Wuhan University, Wuhan, 430072, P. R. China.
  • Li Y The Institute for Advanced Studies, Wuhan University, Wuhan, 430072, P. R. China.
  • Zhu J Laboratory of Synthesis and Natural Products, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, EPFL-SB-ISIC-LSPN, BCH 5304, 1015, Lausanne, Switzerland.
  • Kong W The Institute for Advanced Studies, Wuhan University, Wuhan, 430072, P. R. China.
  • 2018-07-01
Published in:
  • Angewandte Chemie (International ed. in English). - 2019
C−H functionalization
asymmetric synthesis
domino process
homogeneous catalysis
quaternary stereocenters
English The enantioselective synthesis of molecules containing quaternary stereocenters is a field of intense research interest and development. Among the known organic transformations, carbopalladation-initiated domino transformations constitutes a general method for the construction of compounds containing cyclic or spiro quaternary stereocenters. In this Minireview, recent achievements in palladium-catalyzed domino Heck/C-H functionalizations and developments in enantioselective carbopalladation-initiated domino processes are summarized.
Language
  • English
Open access status
closed
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Persistent URL
https://sonar.ch/global/documents/214721
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