Hyperpolarized para-ethanol.
- Mammoli D Institut des Sciences et Ingéniérie Chimiques, Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland.
- Vuichoud B
- Bornet A
- Milani J
- Dumez JN
- Jannin S
- Bodenhausen G
- 2015-02-07
Published in:
- The journal of physical chemistry. B. - 2015
English
We show that an imbalance between the populations of singlet (S) and triplet (T) states in pairs of magnetically equivalent spins can be generated by dissolution dynamic nuclear polarization. In partly deuterated ethanol (CD3(13)CH2OD), this T/S imbalance can be transferred by cross-relaxation to observable, enhanced signals of protons and coupled (13)C.
- Language
-
- English
- Open access status
- green
- Identifiers
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- DOI 10.1021/jp512128c
- PMID 25658134
- Persistent URL
- https://sonar.ch/global/documents/214980
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