Journal article
The First Gold(III) Formate: Evidence for β-Hydride Elimination.
- Kumar R Department of Chemistry, University of Zürich, Winterthurerstrasse 180, 8057, Zürich, Switzerland.
- Krieger JP Department of Chemistry, University of Zürich, Winterthurerstrasse 180, 8057, Zürich, Switzerland.
- Gómez-Bengoa E Departamento de Química Orgánica I, Universidad del Pais Vasco, Apdo 1072, CP-20080, Donostia-San Sebastián, Spain.
- Fox T Department of Chemistry, University of Zürich, Winterthurerstrasse 180, 8057, Zürich, Switzerland.
- Linden A Department of Chemistry, University of Zürich, Winterthurerstrasse 180, 8057, Zürich, Switzerland.
- Nevado C Department of Chemistry, University of Zürich, Winterthurerstrasse 180, 8057, Zürich, Switzerland.
- 2017-09-14
Published in:
- Angewandte Chemie (International ed. in English). - 2017
English
The first stable gold(III) formate and experimental evidence for its β-hydride elimination are described. A catalytic dehydrogenation of formic acid together with mechanistic studies shed light on potential pathways operating in fundamental gold-catalyzed transformations.
- Language
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- English
- Open access status
- closed
- Identifiers
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- DOI 10.1002/anie.201705557
- PMID 28902956
- Persistent URL
- https://sonar.ch/global/documents/215292
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