Journal article
Synthesis and Characterization of Bidentate (P^N)Gold(III) Fluoride Complexes: Reactivity Platforms for Reductive Elimination Studies.
- Nevado C Zurich University, Department of Chemistry, Winterthurerstrasse 190, 8057, Zurich, SWITZERLAND.
- Genoux A University of Zurich, Chemistry, SWITZERLAND.
- Biedrzycki M Universitat Zurich Institut fur Volkswirtschaftslehre, Chemistry, SWITZERLAND.
- Merino E University of Zurich, Chemistry, SWITZERLAND.
- Rivera E University of Zurich, Chemistry, SWITZERLAND.
- Linden A Universitat Zurich, Chemistry, SWITZERLAND.
- 2020-10-05
Published in:
- Angewandte Chemie (International ed. in English). - 2020
English
A new family of cationic, bidentate (P^N)gold(III) fluoride complexes has been prepared and a detailed characterization of the gold-fluoride bond has been carried out. Our results correlate with the observed reactivity of the fluoro ligand, which undergoes facile exchange with both cyano and acetylene nucleophiles. The resulting (P^N)arylgold(III)C(sp) complexes have enabled the first study of reductive elimination on (P^N)gold(III) systems demonstrating that C(sp 2 )-C(sp) bond formation occurs at higher rates than those reported for analogous phosphine-based monodentate systems.
- Language
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- English
- Open access status
- closed
- Identifiers
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- DOI 10.1002/anie.202009359
- PMID 33015997
- Persistent URL
- https://sonar.ch/global/documents/218081
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