Using nature's blueprint to expand catalysis with Earth-abundant metals.
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Bullock RM
Center for Molecular Electrocatalysis, Pacific Northwest National Laboratory, Richland, WA 99352, USA. morris.bullock@pnnl.gov jgchen@columbia.edu gagliard@umn.edu yogi@mit.edu.
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Chen JG
Department of Chemical Engineering, Columbia University, New York, NY 10027, USA. morris.bullock@pnnl.gov jgchen@columbia.edu gagliard@umn.edu yogi@mit.edu.
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Gagliardi L
Department of Chemistry, Minnesota Supercomputing Institute, and Chemical Theory Center, University of Minnesota, Minneapolis, MN 55455, USA. morris.bullock@pnnl.gov jgchen@columbia.edu gagliard@umn.edu yogi@mit.edu.
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Chirik PJ
Department of Chemistry, Princeton University, Princeton, NJ 08544, USA.
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Farha OK
Department of Chemistry and Chemical and Biological Engineering, Northwestern University, Evanston, IL 60208, USA.
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Hendon CH
Department of Chemistry and Biochemistry, University of Oregon, Eugene, OR 97403, USA.
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Jones CW
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA.
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Keith JA
Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA.
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Klosin J
Core R&D, Dow Chemical Co., Midland, MI 48674, USA.
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Minteer SD
Department of Chemistry, University of Utah, Salt Lake City, UT 84112, USA.
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Morris RH
Department of Chemistry, University of Toronto, Toronto, Ontario M5S 3H6, Canada.
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Radosevich AT
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
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Rauchfuss TB
School of Chemical Sciences, University of Illinois, Urbana, IL 61801, USA.
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Strotman NA
Process Research and Development, Merck & Co. Inc., Rahway, NJ 07065, USA.
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Vojvodic A
Department of Chemical and Biomolecular Engineering, University of Pennsylvania, Philadelphia, PA 19104, USA.
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Ward TR
Department of Chemistry, University of Basel, CH-4058 Basel, Switzerland.
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Yang JY
Department of Chemistry, University of California, Irvine, CA 92697, USA.
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Surendranath Y
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA. morris.bullock@pnnl.gov jgchen@columbia.edu gagliard@umn.edu yogi@mit.edu.
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Published in:
- Science (New York, N.Y.). - 2020
English
Numerous redox transformations that are essential to life are catalyzed by metalloenzymes that feature Earth-abundant metals. In contrast, platinum-group metals have been the cornerstone of many industrial catalytic reactions for decades, providing high activity, thermal stability, and tolerance to chemical poisons. We assert that nature's blueprint provides the fundamental principles for vastly expanding the use of abundant metals in catalysis. We highlight the key physical properties of abundant metals that distinguish them from precious metals, and we look to nature to understand how the inherent attributes of abundant metals can be embraced to produce highly efficient catalysts for reactions crucial to the sustainable production and transformation of fuels and chemicals.
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Language
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Open access status
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green
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Persistent URL
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https://sonar.ch/global/documents/231576
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