Crystal structure of chlorido-(2-{1-[2-(4-chloro-phen-yl)hydrazin-1-yl-idene-κN]eth-yl}pyridine-κN)(η(5)-penta-methyl-cyclo-penta-dien-yl)rhodium(III) chloride.
- Devika N Department of Chemistry, BIT Campus, Anna University, Tiruchirappalli 620 024, Tamil Nadu State, India.
- Raja N Institut de Chimie, Université de Neuchâtel, Avenue de Bellevaux 51, CH-2000 Neuchâtel, Switzerland.
- Ananthalakshmi S Department of Chemistry, Urumu Dhanalakshmi College, Tiruchirappalli 620 019, Tamil Nadu State, India.
- Therrien B Institut de Chimie, Université de Neuchâtel, Avenue de Bellevaux 51, CH-2000 Neuchâtel, Switzerland.
- 2015-04-07
Published in:
- Acta crystallographica. Section E, Crystallographic communications. - 2015
N—H⋯Cl hydrogen bond
crystal structure
pentamethylcyclopentadienyl
piano-stool geometry
rhodium(III) complex
English
The cation of the title compound, [Rh(η(5)-C5Me5)Cl(C13H12ClN3)]Cl, adopts a typical piano-stool geometry. The complex is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinyl-idene-pyridine ligand is non-planar, an angle of 54.42 (7)° being observed between the pyridine ring and the aromatic ring of the [2-(4-chloro-phen-yl)hydrazin-1-yl-idene]ethyl group. In the crystal, a weak inter-ionic N-H⋯Cl hydrogen bond is observed.
- Language
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- English
- Open access status
- gold
- Identifiers
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- DOI 10.1107/S205698901500184X
- PMID 25844178
- Persistent URL
- https://sonar.ch/global/documents/24792
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