Journal article
Ionophore-based optical sensors.
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Mistlberger G
Department of Inorganic and Analytical Chemistry, University of Geneva, CH-1211 Geneva 4, Switzerland; email: g.mistlberger@gmail.com , gaston.crespo@unige.ch , eric.bakker@unige.ch.
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Crespo GA
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Bakker E
Published in:
- Annual review of analytical chemistry (Palo Alto, Calif.). - 2014
English
This review provides an overview of the key aspects of designing ionophore-based optical sensors (IBOS). Exact response functions are developed and compared with a simplified, generalized equation. We also provide a brief introduction into less established but promising working principles, namely dynamic response and exhaustive exchange. Absorbance and fluorescence are the main optical readout strategies used in the evaluation of a sensor response, but they usually require a robust referencing technique for real-world applications. Established referencing schemes using IBOS as well as those from other optical sensors are also discussed. Finally, the power of recently developed photoresponsive ion extraction/release systems is outlined and discussed in view of dynamically switchable IBOS or regenerative exhaustive exchange IBOS.
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Language
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Open access status
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closed
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Identifiers
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Persistent URL
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https://sonar.ch/global/documents/248035
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