Journal article
transformation between diphosphinoamines and iminobiphosphines: a reversible P-N-P <--> N=P-P rearrangement triggered by protonation/deprotonation.
Published in:
- Inorganic chemistry. - 2004
English
The protonation of diphosphinoamines attached to pyridine at the ortho-position quantitatively affords the corresponding iminobiphosphine isomers. The starting material can be recovered quantitatively by deprotonation with base. The system represents a new type of molecular switch.
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Open access status
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closed
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Identifiers
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Persistent URL
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https://sonar.ch/global/documents/269705
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