transformation between diphosphinoamines and iminobiphosphines: a reversible P-N-P <--> N=P-P rearrangement triggered by protonation/deprotonation.
Journal article

transformation between diphosphinoamines and iminobiphosphines: a reversible P-N-P <--> N=P-P rearrangement triggered by protonation/deprotonation.

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  • 2004-03-30
Published in:
  • Inorganic chemistry. - 2004
English The protonation of diphosphinoamines attached to pyridine at the ortho-position quantitatively affords the corresponding iminobiphosphine isomers. The starting material can be recovered quantitatively by deprotonation with base. The system represents a new type of molecular switch.
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  • English
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closed
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https://sonar.ch/global/documents/269705
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