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Absolute Configuration from Different Multifragmentation Pathways in Light-Induced Coulomb Explosion Imaging.
Journal article

Absolute Configuration from Different Multifragmentation Pathways in Light-Induced Coulomb Explosion Imaging.

  • Pitzer M Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Kastirke G Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Kunitski M Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Jahnke T Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Bauer T Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Goihl C Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Trinter F Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Schober C Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Henrichs K Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Becht J Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Zeller S Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Gassert H Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Waitz M Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Kuhlins A Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Sann H Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Sturm F Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Wiegandt F Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Wallauer R Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Schmidt LP Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Johnson AS University of Ottawa, Ottawa, ON, K1N 6N5, Canada.
  • Mazenauer M Institute of Chemistry and Biological Chemistry, Zurich University of Applied Sciences, Campus Reidbach, Einsiedlerstrasse 31, 8820, Wädenswil, Switzerland.
  • Spenger B Institute of Chemistry and Biological Chemistry, Zurich University of Applied Sciences, Campus Reidbach, Einsiedlerstrasse 31, 8820, Wädenswil, Switzerland.
  • Marquardt S Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße, 35032, Marburg, Germany.
  • Marquardt S Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße, 35032, Marburg, Germany.
  • Schmidt-Böcking H Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Stohner J Institute of Chemistry and Biological Chemistry, Zurich University of Applied Sciences, Campus Reidbach, Einsiedlerstrasse 31, 8820, Wädenswil, Switzerland.
  • Dörner R Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany.
  • Schöffler M Institute for Nuclear Physics, Johann-Wolfgang-Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438, Frankfurt, Germany. schoeffler@atom.uni-frankfurt.de.
  • Berger R Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße, 35032, Marburg, Germany. robert.berger@uni-marburg.de.
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  • 2016-06-15
Published in:
  • Chemphyschem : a European journal of chemical physics and physical chemistry. - 2016
Coulomb explosion imaging
absolute configuration
chirality
cold target recoil ion momentum spectroscopy
synchrotron radiation
English The absolute configuration of individual small molecules in the gas phase can be determined directly by light-induced Coulomb explosion imaging (CEI). Herein, this approach is demonstrated for ionization with a single X-ray photon from a synchrotron light source, leading to enhanced efficiency and faster fragmentation as compared to previous experiments with a femtosecond laser. In addition, it is shown that even incomplete fragmentation pathways of individual molecules from a racemic CHBrClF sample can give access to the absolute configuration in CEI. This leads to a significant increase of the applicability of the method as compared to the previously reported complete break-up into atomic ions and can pave the way for routine stereochemical analysis of larger chiral molecules by light-induced CEI.
Language
  • English
Open access status
closed
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Persistent URL
https://sonar.ch/global/documents/276364
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