Journal article
Optimization of a heterogeneous Pd-Cu/zeolite Y Wacker catalyst for ethylene oxidation.
- Imbao J Paul Scherrer Institute, 5232 Villigen PSI, Switzerland. maarten.nachtegaal@psi.ch.
- van Bokhoven JA
- Nachtegaal M
- 2020-01-08
Published in:
- Chemical communications (Cambridge, England). - 2020
Materials Chemistry
Electronic, Optical and Magnetic Materials
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
Catalysis
English
Exchanging low amounts of palladium with excess copper in a heterogeneous zeolite Y catalyst leads to high Wacker activity and mitigates activity loss by reducing the extent of palladium sintering. Employing periodic regenerative treatments in oxygen to remove carbon deposits and reoxidize palladium results in the partial (but reversible) recovery of the high initial activity.
- Language
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- English
- Open access status
- hybrid
- Identifiers
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- DOI 10.1039/c9cc08835k
- PMID 31909776
- Persistent URL
- https://sonar.ch/global/documents/278511
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