Journal article
Dicarboxylate-bridged ruthenium complexes as building blocks for molecular nanostructures.
- Kilbas B Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland.
- Mirtschin S
- Riis-Johannessen T
- Scopelliti R
- Severin K
- 2012-05-11
Published in:
- Inorganic chemistry. - 2012
English
Ruthenium complexes with bridging dicarboxylate ligands were combined with 1,2-di-4-pyridylethylene (dpe), 2,4,6-tri-4-pyridyltriazine (4-tpt), or 2,4,6-tri-3-pyridyltriazine (3-tpt) to give a tetranuclear rectangle or hexanuclear coordination cages. The cages display a trigonal-prismatic geometry, as evidenced by single-crystal X-ray crystallography. The 4-tpt-based cages are able to encapsulate polyaromatic molecules such as pyrene, triphenylene, or coronene, whereas the 3-tpt-based cages were found to be incompetent hosts for these guests.
- Language
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- English
- Open access status
- closed
- Identifiers
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- DOI 10.1021/ic300330p
- PMID 22571390
- Persistent URL
- https://sonar.ch/global/documents/27991
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