Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B12H11NH₃].
- Zhang Y Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China. 15868145065@126.com.
- Sun Y Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China. sunyuji1991@163.com.
- Wang T Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China. 21637046@zju.edu.cn.
- Liu J Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China. liujiyong1205@163.com.
- Spingler B Department of Chemistry, University of Zurich, Winterthurerstrasse 190, 8057 Zurich, Switzerland. spingler@chem.uzh.ch.
- Duttwyler S Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China. duttwyler@zju.edu.cn.
- 2018-12-02
Published in:
- Molecules (Basel, Switzerland). - 2018
amide
amidine
borane
boron cluster
dodecaborate
isocyanate
urea
Amides
Amidines
Anions
Boron Compounds
Isocyanates
Models, Molecular
Urea
English
The synthesis and structural characterization of new derivatives of [B12H12]2- is of fundamental interest and is expected to allow for extended applications. Herein we report on the synthesis of a series of amidine, amide, urea and isocyanate derivatives based on the amino-closo-dodecaborate anion [B12H11NH₃]-. Their structures have been confirmed by spectroscopic methods, and nine crystal structures are presented.
- Language
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- English
- Open access status
- gold
- Identifiers
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- DOI 10.3390/molecules23123137
- PMID 30501105
- Persistent URL
- https://sonar.ch/global/documents/298617
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