Journal article
Access to enantioenriched 2,3- and 2,5-dihydrofurans with a fully substituted C2 stereocenter by Pd-catalyzed asymmetric intermolecular Heck reaction.
- Borrajo-Calleja GM Department of Organic Chemistry , University of Geneva , 30 quai Ernest Ansermet , 1211 Geneva-4 , Switzerland . Email: clement.mazet@unige.ch.
- Bizet V Department of Organic Chemistry , University of Geneva , 30 quai Ernest Ansermet , 1211 Geneva-4 , Switzerland . Email: clement.mazet@unige.ch.
- Bürgi T Department of Physical Chemistry , University of Geneva , 30 quai Ernest Ansermet , 1211 Geneva-4 , Switzerland.
- Mazet C Department of Organic Chemistry , University of Geneva , 30 quai Ernest Ansermet , 1211 Geneva-4 , Switzerland . Email: clement.mazet@unige.ch.
- 2017-11-17
Published in:
- Chemical science. - 2015
English
A palladium-catalyzed intermolecular asymmetric Heck reaction with dihydrofurans with a trisubstituted double bond is reported. The use of two different chiral ligands provides access to valuable 2,3- and 2,5-dihydrofurans with a fully substituted C2 stereocenter with high levels of regio- and enantiocontrol.
- Language
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- English
- Open access status
- gold
- Identifiers
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- DOI 10.1039/c5sc01460c
- PMID 29142715
- Persistent URL
- https://sonar.ch/global/documents/34338
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