A mechano- and thermoresponsive luminescent cyclophane.
Sagara YResearch Institute for Electronic Science, Hokkaido University, N20, W10, Kita-Ku, Sapporo 001-0020, Japan. sagara@es.hokudai.ac.jp and Adolphe Merkle Institute, University of Fribourg, Chemin des Verdiers 4, CH-1700 Fribourg, Switzerland. christoph.weder@unifr.ch.
Simon YCAdolphe Merkle Institute, University of Fribourg, Chemin des Verdiers 4, CH-1700 Fribourg, Switzerland. christoph.weder@unifr.ch and School of Polymers and High Performance Materials, the University of Southern Mississippi, 118 College Dr. #5050, Hattiesburg, MS 39406, USA.
Tamaoki NResearch Institute for Electronic Science, Hokkaido University, N20, W10, Kita-Ku, Sapporo 001-0020, Japan. sagara@es.hokudai.ac.jp.
Weder CAdolphe Merkle Institute, University of Fribourg, Chemin des Verdiers 4, CH-1700 Fribourg, Switzerland. christoph.weder@unifr.ch.
2016-04-05
Published in:
Chemical communications (Cambridge, England). - 2016
English
The first fluorescent cyclophane with mechano- and thermoresponsive solid-state fluorescence characteristics is reported. The new cyclophane comprises two 9,10-bis(phenylethynyl)anthracene moieties that are bridged by tetraethylene glycol spacers. The stimuli-responsiveness is based on molecular assembly changes.