Journal article
Self-organisation of dodeca-dendronized fullerene into supramolecular discs and helical columns containing a nanowire-like core.
- Guerra S Institut de Chimie , Université de Neuchâtel , Avenue de Bellevaux 51 , 2000 Neuchâtel , Switzerland . Email: robert.deschenaux@unine.ch.
- Iehl J Laboratoire de Chimie des Matériaux Moléculaires , Université de Strasbourg et CNRS , Ecole Européenne de Chimie , Polymères et Matériaux , 25 rue Becquerel , 67087 Strasbourg Cedex 2 , France . Email: nierengarten@unistra.fr.
- Holler M Laboratoire de Chimie des Matériaux Moléculaires , Université de Strasbourg et CNRS , Ecole Européenne de Chimie , Polymères et Matériaux , 25 rue Becquerel , 67087 Strasbourg Cedex 2 , France . Email: nierengarten@unistra.fr.
- Peterca M Roy & Diana Vagelos Laboratories , Department of Chemistry , University of Pennsylvania , Philadelphia , Pennsylvania 19104-6323 , USA . Email: percec@sas.upenn.edu.
- Wilson DA Roy & Diana Vagelos Laboratories , Department of Chemistry , University of Pennsylvania , Philadelphia , Pennsylvania 19104-6323 , USA . Email: percec@sas.upenn.edu.
- Partridge BE Roy & Diana Vagelos Laboratories , Department of Chemistry , University of Pennsylvania , Philadelphia , Pennsylvania 19104-6323 , USA . Email: percec@sas.upenn.edu.
- Zhang S Roy & Diana Vagelos Laboratories , Department of Chemistry , University of Pennsylvania , Philadelphia , Pennsylvania 19104-6323 , USA . Email: percec@sas.upenn.edu.
- Deschenaux R Institut de Chimie , Université de Neuchâtel , Avenue de Bellevaux 51 , 2000 Neuchâtel , Switzerland . Email: robert.deschenaux@unine.ch.
- Nierengarten JF Laboratoire de Chimie des Matériaux Moléculaires , Université de Strasbourg et CNRS , Ecole Européenne de Chimie , Polymères et Matériaux , 25 rue Becquerel , 67087 Strasbourg Cedex 2 , France . Email: nierengarten@unistra.fr.
- Percec V Roy & Diana Vagelos Laboratories , Department of Chemistry , University of Pennsylvania , Philadelphia , Pennsylvania 19104-6323 , USA . Email: percec@sas.upenn.edu.
- 2017-11-17
Published in:
- Chemical science. - 2015
English
Twelve chiral and achiral self-assembling dendrons have been grafted onto a [60]fullerene hexa-adduct core by copper-catalyzed alkyne azide "click" cycloaddition. The structure adopted by these compounds was determined by the self-assembling peripheral dendrons. These twelve dendrons mediate the self-organisation of the dendronized [60]fullerene into a disc-shaped structure containing the [60]fullerene in the centre. The fullerene-containing discs self-organise into helical supramolecular columns with a fullerene nanowire-like core, forming a 2D columnar hexagonal periodic array. These unprecedented supramolecular structures and their assemblies are expected to provide new developments in chiral complex molecular systems and their application to organic electronics and solar cells.
- Language
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- English
- Open access status
- gold
- Identifiers
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- DOI 10.1039/c5sc00449g
- PMID 29142695
- Persistent URL
- https://sonar.ch/global/documents/44626
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