Back
[ReO3(bipy)]+[X]--catalyzed aldehyde olefination: carbene and phosphorane intermediates.
Journal article

[ReO3(bipy)]+[X]--catalyzed aldehyde olefination: carbene and phosphorane intermediates.

  • Zhang X Laboratorium für Organische Chemie, Eidgenossische Technische Hochschule, ETH Zürich, Switzerland.
  • Chen P
  • 2003-04-17
Published in:
  • Chemistry (Weinheim an der Bergstrasse, Germany). - 2003
English The aldehyde olefination reaction, catalyzed by cationic high-valent oxorhenium complexes, shows evidence of the intermediacy of both carbene complexes and phosphoranes. The solution-phase reaction is facile and amenable to tuning and is, hence, likely to prove to be of practical significance. Individual steps in the catalytic cycle are observed in the gas phase. Catalytic competence of each of the putative intermediates can be demonstrated.
Language
  • English
Open access status
closed
Identifiers
Persistent URL
https://sonar.ch/global/documents/52547
Statistics
Document views: 30 File downloads: