Silica-supported isolated molybdenum di-oxo species: formation and activation with organosilicon agent for olefin metathesis.
Published in:
- Chemical communications (Cambridge, England). - 2018
English
A well-defined silica-supported molybdenum dioxo species, ([triple bond, length as m-dash]SiO)2Mo(O)2, is prepared by grafting Mo(O)2[OSi(OtBu)3]2 on partially dehydroxylated silica SiO2-700, followed by thermal treatment under high-vaccum and calcination. Activated by an organosilicon agent the resulting material is active for olefin metathesis at 30 °C.
-
Language
-
-
Open access status
-
green
-
Identifiers
-
-
Persistent URL
-
https://sonar.ch/global/documents/57732
Statistics
Document views: 15
File downloads: