Journal article

Silica-supported isolated molybdenum di-oxo species: formation and activation with organosilicon agent for olefin metathesis.

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  • 2018-04-04
Published in:
  • Chemical communications (Cambridge, England). - 2018
English A well-defined silica-supported molybdenum dioxo species, ([triple bond, length as m-dash]SiO)2Mo(O)2, is prepared by grafting Mo(O)2[OSi(OtBu)3]2 on partially dehydroxylated silica SiO2-700, followed by thermal treatment under high-vaccum and calcination. Activated by an organosilicon agent the resulting material is active for olefin metathesis at 30 °C.
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  • English
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green
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https://sonar.ch/global/documents/57732
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