Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system.
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Manson JL
Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, WA 99004, USA. jmanson@ewu.edu.
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Schlueter JA
Materials Science Division, Argonne National Laboratory, Argonne, IL 60439, USA.
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Garrett KE
Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, WA 99004, USA. jmanson@ewu.edu.
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Goddard PA
Department of Physics, University of Warwick, Coventry CV4 7AL, UK.
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Lancaster T
Center for Materials Physics, Durham University, Durham DH1 3LE, UK.
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Möller JS
Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU, UK.
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Blundell SJ
Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU, UK.
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Steele AJ
Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU, UK.
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Franke I
Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU, UK.
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Pratt FL
ISIS Pulsed-Muon Facility, STFC Rutherford Appleton Laboratory, Chilton, Oxfordshire OX11 0QX, UK.
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Singleton J
National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
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Bendix J
Department of Chemistry, University of Copenhagen, Copenhagen DK-2100, Denmark.
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Lapidus SH
X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Lemont IL 60439, USA.
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Uhlarz M
Hochfeld-Magnetlabor Dresden (HLD-EMFL), Helmholtz-Zentrum Dresden Rossendorf, DE-01314, Dresden, Germany.
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Ayala-Valenzuela O
National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
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McDonald RD
National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
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Gurak M
National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
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Baines C
Laboratory for Muon-Spin Spectroscopy, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland.
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Published in:
- Chemical communications (Cambridge, England). - 2016
English
The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.
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green
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https://sonar.ch/global/documents/858
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