Journal article

Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system.

  • Manson JL Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, WA 99004, USA. jmanson@ewu.edu.
  • Schlueter JA Materials Science Division, Argonne National Laboratory, Argonne, IL 60439, USA.
  • Garrett KE Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, WA 99004, USA. jmanson@ewu.edu.
  • Goddard PA Department of Physics, University of Warwick, Coventry CV4 7AL, UK.
  • Lancaster T Center for Materials Physics, Durham University, Durham DH1 3LE, UK.
  • Möller JS Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU, UK.
  • Blundell SJ Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU, UK.
  • Steele AJ Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU, UK.
  • Franke I Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU, UK.
  • Pratt FL ISIS Pulsed-Muon Facility, STFC Rutherford Appleton Laboratory, Chilton, Oxfordshire OX11 0QX, UK.
  • Singleton J National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
  • Bendix J Department of Chemistry, University of Copenhagen, Copenhagen DK-2100, Denmark.
  • Lapidus SH X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Lemont IL 60439, USA.
  • Uhlarz M Hochfeld-Magnetlabor Dresden (HLD-EMFL), Helmholtz-Zentrum Dresden Rossendorf, DE-01314, Dresden, Germany.
  • Ayala-Valenzuela O National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
  • McDonald RD National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
  • Gurak M National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
  • Baines C Laboratory for Muon-Spin Spectroscopy, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland.
Show more…
  • 2016-10-08
Published in:
  • Chemical communications (Cambridge, England). - 2016
English The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.
Language
  • English
Open access status
green
Identifiers
Persistent URL
https://sonar.ch/global/documents/858
Statistics

Document views: 20 File downloads:
  • Full-text: 0