![Use of calix[4]arenes in the redox chemistry of lanthanides: the reduction of dinitrogen by a calix[4]arene-samarium complex.](/static/images/no-image.png)
Journal article
Use of calix[4]arenes in the redox chemistry of lanthanides: the reduction of dinitrogen by a calix[4]arene-samarium complex.
- Guillemot G Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne, BCH-LCIB, CH-1015 Lausanne, Switzerland. geoffroy.guillemot@univ-paris5.fr
- Castellano B
- Prangé T
- Solari E
- Floriani C
- 2007-06-05
Published in:
- Inorganic chemistry. - 2007
Calixarenes
Lanthanoid Series Elements
Molecular Structure
Nitrogen
Oxidation-Reduction
Phenols
Samarium
English
The synthesis and structural characterization of a samarium-dinitrogen complex supported by a calix[4]arene ligand in which the N-N bond distance has been stretched to 1.611(16) Angstrom are described. The central mu(3)-eta(2):eta(2):eta(2)-hydrazido tetraanion formed is bonded to three Sm(III) centers with an overall butterfly-type arrangement.
- Language
-
- English
- Open access status
- closed
- Identifiers
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- DOI 10.1021/ic700787d
- PMID 17542578
- Persistent URL
- https://sonar.ch/global/documents/102319
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